అవలోకనం

SPPS is an exciting method to produce a wide variety of functional oxide ceramic coatings, employing appropriate solution precursors in contrast to powder feedstock in case of conventional plasma spraying. The technique utilizes aqueous/organic chemical precursor solutions fed into the high temperature plasma plume through a dedicated delivery device. The solvent vaporizes as the droplet travel downstream to form solid particles and are heated & accelerated to the substrate to form finely structured coating deposits.

Key Features

The SPPS process opens new avenues for developing compositionally complex functional oxide coatings, with the following benefits: 

  • ability to create nanosized microstructures without any feeding problems normally associated with powder-based systems,
  • flexible, rapid exploration of novel precursor compositions and their combinations
  • circumvention of expensive powder feedstock preparation steps,
  • better control over the chemistry of the deposit
     

Schematic of SPPS process
Schematic of SPPS process
YSZ coating with vertical cracks & distributed pores
YSZ coating with vertical cracks & distributed pores

Potential Applications

  • YSZ based TBCs for gas/steam turbine applications
  • Pure α-Al2O3 based dielectric coatings
  • Graphene films for wear resistance, energy storage applications
  • LSM, LiFePO4, etc for electrodes (anode & cathode) of SOFCs/Li-Ion Batteries
  • Ferrites and Titania for photocatalytic applications
  • Solar absorption coatings
  • High entropy alloy / Nanocomposite coatings for hydrogen generation

స్థితి

  • Developed wide ranging functional coatings for diverse industrial applications
  • Prototype demonstration of various coatings 

Intellectual Property Development Index (IPDI)

Level 1 2 3 4 5 6 7 8 9 10
వివరణ Basic concepts and understanding of underlying scientific principles Shortlisting possible applications Research to prove technical feasibility for targeted application Coupon level testing in simulated conditions Check repeatability/consistency Prototype testing in real-life conditions Check repeatability/consistency Reassessing feasibility (IP, competition technology, commercial) Initiate technology transfer Support in stabilizing production
స్థితి

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  • Easwaramoorthi Ramasamy, Sivakumar Govindarajan, Shrikant Joshi, Production of Graphene based Materials by Thermal Spray, ARCI patent appl. no. 2626/DEL/2015 

  • G. Sivakumar, R.O. Dusane, and S.V. Joshi, “Understanding the Formation of Vertical cracks in Solution Precursor Plasma Sprayed Yttria-Stabilized-Zirconia Coatings”, Journal of American Ceramic Society, 97(11), 3396-3406, 2014
  • G. Sivakumar, Rajiv O. Dusane and Shrikant V. Joshi, A novel approach to process phase pure α-Al2O3 coatings by solution precursor plasma spraying’, Journal of the European Ceramic Society, 33 (2013) 2823–2829